Publication:
Enhanced photocatalytic and antimicrobial performance of a multifunctional Cu-loaded nanocomposite under UV light: theoretical and experimental study

Publisher DOI
10.1039/d2nr01710e
Date
2022-05-18

Type
Article
Authors
Abd Elkodous, M.
Abdel Maksoud, M. I. A.
Alias, Nurhaswani
Abdelsalam, Hazem
Ibrahim, Medhat A.
Elsayed, Mohamed A.
Kawamura, Go
Lockman, Zainovia
Tan, Wai Kian
Matsuda, Atsunori
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Publisher
Royal Society of Chemistry
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Source
https://pubs.rsc.org/en/content/articlelanding/2022/NR/D2NR01710E
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Abstract
Due to modern industrialization and population growth, access to clean water has become a global challenge. In this study, a metal–semiconductor heterojunction was constructed between Cu NPs and the Co0.5Ni0.5Fe2O4/SiO2/TiO2 composite matrix for the photodegradation of potassium permanganate, hexavalent chromium Cr(VI) and p-nitroaniline (pNA) under UV light. In addition, the electronic and adsorption properties after Cu loading were evaluated using density functional theory (DFT) calculations. Moreover, the antimicrobial properties of the prepared samples toward pathogenic bacteria and unicellular fungi were investigated. Photocatalytic measurements show the outstanding efficiency of the Cu-loaded nanocomposite compared to that of bare Cu NPs and the composite matrix. Degradation efficiencies of 44% after 80 min, 100% after 60 min, and 65% after 90 min were obtained against potassium permanganate, Cr(VI), and pNA, respectively. Similarly, the antimicrobial evaluation showed high ZOI, lower MIC, higher protein leakage amount, and cell lysis of nearly all microbes treated with the Cu-loaded nanocomposite.
Description
Keywords
experimental, theoretical, nanocomposite, photocatalytic
Citation
Abd Elkodous, M., El-Khawaga, A. M., Abdel Maksoud, M. I. A., El-Sayyad, G. S., Alias, N., Abdelsalam, H., Ibrahim, M. A., Elsayed, M. A., Kawamura, G., Lockman, Z., Tan, W. K., & Matsuda, A. (2022). Enhanced photocatalytic and antimicrobial performance of a multifunctional Cu-loaded nanocomposite under UV light: theoretical and experimental study. Nanoscale, 14(23), 8306–8317. https://doi.org/10.1039/d2nr01710e
Journal Title
Nanoscale
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Volume
14
Issue
23
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© 2023 by the authors. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.